Nondestructive Detection of Moisture Content in Palm Oil by Using Portable Vibrational Spectroscopy and Optimal Prediction Algorithms.

Rapid and nondestructive measurement of moisture content in crude palm oil is essential for promoting the shelf-stability and quality. In this research, micro NIR spectrometer coupled with a multivariate calibration model was used to collect and analyse fingerprinted information from palm oil samples at different moisture contents. Several preprocessing methods such as standard normal variant (SNV), multiplicative scatter correction (MSC), Savitzky-Golay first derivative (SGD1), Savitzky-Golay second derivative (SGD2) together with partial least square (PLS) regression techniques, full PLS, interval PLS (iPLS), synergy interval PLS (SiPLS), genetic algorithm PLS (GAPLS), and successive projection algorithm PLS (SPA-PLS) were comparatively employed to construct an optimum quantitative prediction model for moisture content in crude palm oil. The models were evaluated according to the coefficient of determination and root mean square error in calibration (Rc and RMSEC) and prediction (Rp and RMSEC) set, respectively. The model SGD1 + SiPLS was the optimal novel algorithm obtained among the others with the performance of Rc = 0.968 and RMSEC = 0.468 in the calibration set and Rp = 0.956 and RMSEP = 0.361 in the prediction set. The results showed that rapid and nondestructive determination of moisture content in palm oil is feasible and this would go a long way to facilitating quality control of crude palm oil.

Rapid authentication of coffee bean varieties of different forms by using a pocket-sized spectrometer and multivariate data modelling.

Coffee is the most consumed beverage and the second most valuable traded commodity in the world. In this current study, a pocket-sized spectrometer and multivariate analysis were used for rapid authentication of coffee varieties (Arabica and Robusta) in three states to check mislabelling (food fraud). Two main coffee varieties were collected from different locations in Africa. The samples were scanned in the 740-1070 nm wavelength and the spectral data were pre-treated with several methods: mean centering (MC), multiplicative scatter correction (MSC), first derivative (FD), second derivative (SD) and standard normal variate (SNV) independently while partial least squares discriminate analysis (PLS-DA), K-nearest neighbour (KNN) and support vector machine (SVM) were used to comparatively build the prediction models for coffee beans (raw, roasted and powdered). The performances of the models were evaluated by using accuracy and efficiency. Among the classification methods developed, the best results were obtained for the following: raw coffee bean SD-SVM had an accuracy of 0.92 and efficiency of 0.82. For roasted coffee beans, SD-KNN had an accuracy of 0.92 and efficiency of 0.87, while for roasted powdered coffee, FD-KNN showed an accuracy of 0.97 and efficiency of 0.97. These finding reveals that for a more accurate differentiation of coffee beans, the roasted powder offers the best results. The obtained results showed that a pocket-sized spectrometer coupled with chemometrics could be employed to provide accurate and rapid authentication of different categories of coffee bean varieties.

Innovative and rapid analysis for rice authenticity using hand-held NIR spectrometry and chemometrics.

Rice is the second most important food staple worldwide and the demand will continue to increase with the growth of the world population. As reports grow that frauds is prevalent in many supply chains there is the need for an effective and rapid technique for monitoring the authenticity and quality of rice. This study investigated the novel application of hand-held NIR spectrometry coupled to chemometric for the estimation of rice authenticity and quality in real time. A total of 520 rice samples from different quality grades (high quality, mid quality and low quality) and different countries (Ghana, Thailand, and Vietnam) of origin were used. Among the pre-processing methods used multiplicative scatter correction (MSC) was found to be superior. Principal component analysis (PCA) was used to extract relevant information from the spectral data set and the results showed that rice samples of different categories could be clearly clustered under the first three PCs using the MSC preprocessing method. The performance of K-nearest neighbor (KNN) revealed that for authentication of rice quality grades, the classification rate gave 91.62% and 91.81% in training set and prediction set respectively while identification rate based on different country of origin was 90.84% and 90.64% in both training set and prediction set respectively. For the differentiation of local rice from the imported, KNN and SVM all had 100% in both the training set and prediction set. These gives very strong evidence that hand-held spectrometry coupled with MSC-PCA-KNN could successfully be used to provide rapid and nondestructive classification of rice samples according to different quality grades, geographical origin and imported versus locally produced rice. This technique could enhance the work of quality control inspectors both from industry and regulatory perspectives for the rapid detection of rice integrity and fraud issues.